Hot melt adhesive

ABSTRACT

The present invention provides a hot melt adhesive for high-speed coating and spiral coating at low temperature. The hot melt adhesive has excellent adhesion to polyethylene and nonwoven fabric, and is suitable for disposable products. The hot melt adhesive comprises: (A) a propylene homopolymer having a melting point of 100° C. or lower which is obtainable by polymerizing propylene using a metallocene catalyst; and (B) an ethylene-based copolymer.

FIELD OF THE INVENTION

The present invention relates to a hot melt adhesive, and moreparticularly to a hot melt adhesive which is used in the field ofdisposable products typified by a diaper and a napkin.

BACKGROUND OF THE INVENTION

A synthetic rubber-based hot melt adhesive containing a thermoplasticblock copolymer as a main component has widely been used as a hot meltadhesive which is used in disposable products such as a diaper and anapkin and is applied to a base material thereof, for example, anonwoven fabric, a tissue, a polyethylene film and the like.

In case of producing the disposable products, a film or a nonwovenfabric is coated with a hot melt adhesive, and high-speed coating issometimes employed so as to enhance the production efficiency of thedisposable products. However, the synthetic rubber-based hot meltadhesive may be sometimes scattered when applied at a high speed.

One of means for enhancing the production efficiency of the disposableproducts includes a method in which an olefin-based hot melt adhesivetypified by an ethylene-propylene copolymer is applied at a high speed.

WO 2003/087172 A1, JP 2003-533551 A and JP 2003-518171 A disclose a hotmelt adhesive containing an olefin polymer as a main component. It isknown that an olefin-based hot melt adhesive is commonly more suitablefor use in paper processing than use in disposable products.

WO 2003/087172 A1 discloses that a propylene polymer is used as a rawmaterial for a hot melt adhesive. However, the hot melt adhesive ofPatent Literature 1 does not have sufficient adhesion to a polyethylenefilm. A diaper, a sanitary napkin and the like often have a structure inwhich an absorber constituted by a pulp, an absorbent polymer and thelike is wrapped in a tissue and the outside thereof is covered with anonwoven fabric, a polyethylene film and the like. Therefore, it isrequired for the hot melt adhesive for disposable products to have astrong adhesive strength to the polyethylene film.

JP 2003-533551 A discloses a polyolefin-based hot melt adhesive fordisposable products. In case of spiral coating of a polyethylene filmwith the hot melt adhesive of JP 2003-533551 A, it is necessary todecrease the viscosity by increasing a coating temperature so as to copewith a complicated coating pattern. As shown in JP 2003-533551 A, thecoating temperature of the hot melt adhesive is set to high temperature(350° F. to 365° F.). However, when the polyethylene film is coated withthe hot melt adhesive at the above temperature, the film would be meltedand the coated hot melt adhesive would shrink due to cooling, resultingin the formation of wrinkles in the film.

JP 2003-518171 A discloses a propylene-based hot melt adhesive. However,it is also difficult for the hot melt adhesive of JP 2003-518171 A to beapplied by spiral coating at low temperature, as is the case with thehot melt adhesive of JP 2003-533551 A, and also it is hardly to say thatthe peel strength between nonwoven fabrics is sufficient.

OBJECT OF THE INVENTION

An object of the present invention is to provide a hot melt adhesive,which is excellent in high-speed coating and spiral coating at lowtemperature and is also excellent in adhesion to polyethylene and anonwoven fabric; and disposable products obtainable by the hot meltadhesive.

The present inventors have intensively studied and found that it ispossible to obtain a hot melt adhesive which is excellent in high-speedcoating and is excellent in spiral coating at low temperature, and isalso excellent in adhesion to polyethylene and a nonwoven fabric, when apropylene homopolymer having narrow molecular weight distribution andalso having a low melting point is blended with an ethylene-basedcopolymer, and that such a hot melt adhesive is suitable for disposableproducts. Thus, the present invention has been completed.

Furthermore, the present inventors has found that, when anethylene/octene copolymer is used as the ethylene-based copolymer whichis a component to be blended in the hot melt adhesive, a coating patternof the hot melt adhesive becomes inconspicuous, resulting insatisfactory appearance of the disposable products.

That is, the present invention provides a hot melt adhesive including:(A) a propylene homopolymer having a melting point of 100° C. or lowerwhich is obtainable by polymerizing propylene using a metallocenecatalyst; and (B) an ethylene-based copolymer.

The present invention provides the hot melt adhesive, in an embodiment,wherein the ethylene-based copolymer (B) is an ethylene/α-olefincopolymer which is obtainable by polymerization using a metallocenecatalyst.

The present invention provides, as a preferred embodiment, the hot meltadhesive, wherein the ethylene/α-olefin copolymer (B) contains at leastone selected from an ethylene/propylene copolymer and an ethylene/octenecopolymer.

The present invention provides, as another embodiment, the hot meltadhesive, further including: (C) a tackifier resin; and (D) an oil.

The present invention provides, as still another embodiment, the hotmelt adhesive including: (E) a wax, wherein the wax (E) includes a waxmodified with carboxylic acid and/or carboxylic anhydride.

The present invention provides, as another preferred embodiment, the hotmelt adhesive having a melt viscosity at 150° C. of 7,000 mPa·s or less.

The present invention provides, as a second aspect, disposable productsobtainable by using the above hot melt adhesive.

SUMMARY OF THE INVENTION

Since the hot melt adhesive of the present invention includes: (A) apropylene homopolymer having a melting point of 100° C. or lower whichis obtainable by polymerizing propylene using a metallocene catalyst;and (B) an ethylene-based copolymer, the hot melt adhesive is excellentin high-speed coating and spiral coating at low temperature, and is alsoexcellent in adhesion to a polyethylene film and a nonwoven fabric.

When the ethylene-based copolymer (B) is an ethylene/α-olefin copolymerwhich is obtainable by polymerization using a metallocene catalyst, thehot melt adhesive is more excellent in adhesion to a polyethylene filmand a nonwoven fabric while maintaining the high-speed coatability andthe spiral coatability at low temperature.

In the hot melt adhesive of the present invention, when theethylene/α-olefin copolymer (B) contains at least one selected from anethylene/propylene copolymer and an ethylene/octene copolymer, thespiral coatability at low temperature is more improved. When theethylene/octene copolymer is contained, a coating pattern of theadhesive becomes inconspicuous in case of coating adherends such as apolyethylene film and a nonwoven fabric by means of spiral coating.

When the hot melt adhesive of the present invention further includes:(C) a tackifier resin; and (D) an oil, the hot melt adhesive becomesmore excellent in adhesion to a polyethylene film and a nonwoven fabricwhile maintaining the high-speed coatability and the spiral coatabilityat low temperature.

When the hot melt adhesive of the present invention includes: (E) a wax,and the wax (E) is a wax modified with carboxylic acid and/or carboxylicanhydride, the hot melt adhesive becomes still more excellent inadhesion to a polyethylene film and a nonwoven fabric while maintainingthe high-speed coatability and the spiral coatability at lowtemperature.

When the hot melt adhesive of the present invention has a melt viscosityat 150° C. of 7,000 mPa·s or less, it becomes possible to be applied byspiral coating at low temperature of about 150° C. and a film as anadherend is less likely to be melted at high temperature, and also thefilm is less likely to shrink even though the temperature of theadhesion part of the film decreases.

Since the disposable products of the present invention are obtainableusing the above hot melt adhesive, it is efficiently produced in ahigh-speed coating line. Because of low temperature of about 150° C.,the coating line achieves high safety and peeling of a nonwoven fabricand a film does not occur. The coating pattern is less likely to beconspicuous, resulting in excellent appearance.

DETAILED DESCRIPTION OF THE INVENTION

The hot melt adhesive according to the present invention contains, asessential components, two components: (A) a propylene homopolymer havinga melting point of 100° C. or lower which is obtainable by polymerizingpropylene using a metallocene catalyst; and (B) an ethylene-basedcopolymer.

In the present invention, the propylene homopolymer (A) refers to ahomopolymer of propylene, which is produced by using a metallocenecatalyst as a polymerization catalyst. The melting point of thepropylene homopolymer (A) is 100° C. or lower, more preferably from 60to 90° C., and most preferably from 65 to 85° C.

The melting point refers to a value measured by differential scanningcalorimetry (DSC). Specifically, after weighing 10 mg of a sample in analuminum container, the measurement is carried out at temperature riserate of 5° C./minute using DSC6220 (trade name) manufactured by SIINanoTechnology Inc, and the temperature of a top of a fusion peak refersto the melting point.

When propylene is polymerized using a metallocene catalyst, a propylenehomopolymer having (i) crystallinity and (ii) very narrow molecularweight distribution is synthesized.

The above (i) means that complete isotacticity and syndiotacticity canbe optionally controlled. Therefore, a polymer, in which arrangement,ratio and the like of methyl groups is uniform, is obtained withoutcausing deviation of crystallinity, and a low crystalline site that cancause decrease in adhesive force is less likely to be formed.

With respect to (ii), when molecular weight distribution of thepropylene homopolymer (A) is indicated by polydispersity (Mw/Mn), it isfrom 1.0 to 3.0. The propylene homopolymer having polydispersity of 1.0to 3.0 is excellent in adhesion. The molecular weight distribution is aconcept which indicates distribution of a molecular weight of asynthetic polymer, and a ratio (Mw/Mn) of a weight average molecularweight (Mw) to a number average molecular weight (Mn) serves as anindicator. In the present invention, the molecular weight distributionis measured by gel permeation chromatography (GPC).

Examples of the propylene homopolymer (A) include: (A1) a propylenehomopolymer having a weight average molecular weight of 60,000 or less;and (A2) a propylene homopolymer having a weight average molecularweight of more than 60,000.

The weight average molecular weight of the propylene homopolymer (A1) ispreferably from 30,000 to 60,000, and particularly preferably from30,000 to 55,000.

The weight average molecular weight of the propylene homopolymer (A2) ismore than 60,000, preferably more than 60,000 and 90,000 or less, andmore preferably more than 60,000 and 80,000 or less.

Examples of a commercially available product of the propylenehomopolymer (A1) include L-MODU X400S (trade name) manufactured byIdemitsu Kosan Co., Ltd., and examples of a commercially availableproduct of the propylene homopolymer (A2) include L-MODU X600S (tradename) manufactured by Idemitsu Kosan Co., Ltd.

In the present invention, the propylene homopolymer (A) preferablycontains the propylene homopolymer (A1), and also may contain the (A2).

The propylene homopolymer (A) may not contain the propylene homopolymer(A1), and may contain only the propylene homopolymer (A2).

In the present invention, the amount of the propylene homopolymer (A) ispreferably from 60 to 95 parts by weight, and particularly preferablyfrom 70 to 90 parts by weight, based on 100 parts by weight of the totalweight of the propylene homopolymer (A) and the ethylene-based copolymer(B).

When the propylene homopolymer (A) contains both the propylenehomopolymer (A1) and the propylene homopolymer (A2), a weight ratio ofboth polymer is preferably from 1:3 to 3:2 ((A1):(A2)).

The weight average molecular weight (Mw) means a value measured by gelpermeation chromatography (GPC). Specifically, the value can be measuredby using the following apparatus and measuring method. RI manufacturedby Wators Corporation is used as a detector. TSKGEL GMHHR-H(S) HTmanufactured by TOSOH CORPORATION is used as a GPC column. A sample isdissolved in 1,2,4-trichlorobenzene and allowed to flow at a flow rateof 1.0 ml/min and a measuring temperature of 145° C., and then theweight average molecular weight is determined by conversion of amolecular weight using a calibration curve derived based onpolypropylene.

Since the number average molecular weight (Mn) is also determined by thesame method, the molecular weight distribution is also calculated byGPC.

When the hot melt adhesive of the present invention contains thepropylene homopolymer (A1), spiral coatability at low temperature isimproved while maintaining adhesion to a polyethylene film and anonwoven fabric.

In the present invention, the ethylene-based copolymer (B) refers to acopolymer of ethylene and a copolymerizable monomer which iscopolymerizable with ethylene.

Examples of the copolymerizable monomer include:

α-olefin such as ethylene, propylene, octene and butene;

carboxylic acid (esters) such as vinyl acetate, (meth)acrylic acid,(meth)acrylic acid ester, maleic acid and maleic acid ester;

carboxylic anhydrides such as maleic anhydride, phthalic anhydride andsuccinic anhydride; and the like.

These copolymerizable monomers may be copolymerized alone with ethylene,or two or more kinds of copolymerizable monomers may be copolymerized.

As used herein, (meth)acrylic acid refers to a concept including bothmethacrylic acid and acrylic acid. Specific examples of the(meth)acrylic acid ester include methyl acrylate, ethyl acrylate,n-propyl acrylate, n-butyl acrylate, isobutyl acrylate, 2-ethylhexylacrylate, 2-hydroxyethyl acrylate, isooctyl acrylate, methylmethacrylate, ethyl methacrylate, glycidyl methacrylate and the like.

Therefore, in the present invention, examples of the ethylene-basedcopolymer (B) include an ethylene/α-olefin copolymer, anethylene/carboxylic acid copolymer, an ethylene/carboxylic acid estercopolymer and an ethylene/carboxylic anhydride copolymer.

The ethylene copolymer (B) of the present invention is preferably theethylene/α-olefin copolymer. The ethylene/α-olefin copolymer isparticularly preferably an ethylene/α-olefin copolymer obtained bypolymerization using a metallocene catalyst.

When the hot melt adhesive of the present invention contains theethylene/α-olefin copolymer obtained by polymerization using ametallocene catalyst, the spiral coatability at low temperature isimproved and the adhesion to a polyethylene film and a nonwoven fabricis more excellent.

Examples of the ethylene/α-olefin copolymer obtained by polymerizationusing a metallocene catalyst include an ethylene/propylene copolymer, anethylene/octene copolymer, an ethylene/butene copolymer and anethylene/propylene/butene copolymer, and the ethylene/propylenecopolymer and the ethylene/octene copolymer are particularly desirable.

When the hot melt adhesive of the present invention contains at leastone selected from the ethylene/propylene copolymer and theethylene/octene copolymer, the spiral coatability at low temperature ismore improved.

A melt index at 230° C. of the ethylene/propylene copolymer ispreferably 200 g/10 minutes or less, more preferably from 10 to 50 g/10minutes, and most preferably from 20 to 30 g/10 minutes. When the meltindex is within the above range, the peel strength of the hot meltadhesive is improved.

As used herein, the melt index means an indicator which indicatesfluidity of a resin. A given amount of a synthetic resin is heated at aprescribed temperature (for example, 230° C.) in a cylindrical vesselheated by a heater, pressurized under a prescribed load (for example,2.16 kg) and then extruded through an opening (nozzle) provided at thebottom of the vessel, and thus the melt index is denoted by the amountof the resin extruded per 10 minutes. A unit (g/10 minutes) is used. Themelt index is measured by the measuring method defined in ASTM D1238.

The hot melt adhesive containing the ethylene/octene copolymer canimprove appearance of disposable products since a coating pattern of theadhesive is inconspicuous even if adherends such as a polyethylene filmand a nonwoven fabric are coated by spiral coating with the adhesive.

As a preferred embodiment of the present invention, when theethylene-based copolymer (B) is the ethylene/propylene copolymerobtained by polymerization using a metallocene catalyst, the propylenehomopolymer (A) preferably contains both the propylene homopolymer (A1)and the propylene homopolymer (A2). When the component (A) and thecomponent (B) are used in combination as mentioned above, the peelstrength of the hot melt adhesive is remarkably improved.

As another preferred embodiment of the present invention, when theethylene-based copolymer (B) is the ethylene/octene copolymer obtainedby polymerization using a metallocene catalyst, the propylenehomopolymer (A) preferably contains only the propylene homopolymer (A1).When the component (A) and the component (B) are used in combination asmentioned above, the coating pattern of the hot melt adhesive becomesscarcely conspicuous, and thus the appearance of disposable products isremarkably improved.

The ethylene/octene copolymer is preferably a block copolymer ascompared with a random copolymer. When the ethylene/octene copolymer isa block copolymer, the hot melt adhesive excellent in peel strength isobtainable.

It is preferred that the hot melt adhesive for disposable products ofthe present invention further includes: (C) a tackifier resin. Thetackifier resin (C) is preferably blended in the amount of 20 to 180parts by weight, more preferably 40 to 150 parts by weight, andparticularly preferably 60 to 150 parts by weight, based on 100 parts byweight of the total weight of the propylene homopolymer (A) and the wax(B).

When the tackifier resin (C) is blended in the above proportion, the hotmelt adhesive can be applied by spiral coating at low temperature of150° C. or lower. Furthermore, the hot melt adhesive can be uniformlyapplied to a polyethylene film and a nonwoven fabric, and thus theobtained adhesive is more suitable for the production of disposableproducts.

Examples of the tackifier resin (C) include a natural rosin, a modifiedrosin, a hydrogenated rosin, a glycerol ester of a natural rosin, aglycerol ester of a modified rosin, a pentaerythritol ester of a naturalrosin, a pentaerythritol ester of a modified rosin, a pentaerythritolester of a hydrogenated rosin, a copolymer of a natural terpene, aterpolymer of a natural terpene, hydrogenated derivatives of a copolymerof a hydrogenated terpene, a polyterpene resin, hydrogenated derivativesof a phenol-based modified terpene resin, an aliphatic petroleumhydrocarbon resin, hydrogenated derivatives of an aliphatic petroleumhydrocarbon resin, an aromatic petroleum hydrocarbon resin, hydrogenatedderivatives of an aromatic petroleum hydrocarbon resin, a cyclicaliphatic petroleum hydrocarbon resin, and hydrogenated derivatives of acyclic aliphatic petroleum hydrocarbon resin. These tackifier resins canbe used alone, or in combination. It is also possible to use, as thetackifier resin, a liquid type tackifier resin as long as it has acolorless to pale yellow color tone and has substantially no odor, andalso has satisfactory thermal stability. Taking these characteristicsinto consideration comprehensively, the tackifier resin is preferablyhydrogenated derivatives of resins, and particularly preferably ahydrogenated dicyclopentadiene-based resin.

It is possible to use, as the tackifier resin (C), commerciallyavailable products. Examples of these commercially available productsinclude Alcon P100 (trade name) and Alcon M100 (trade name) manufacturedby Arakawa Chemical Industries, Ltd.; Clearon M105 (trade name)manufactured by YASUHARA CHEMICAL CO., LTD.; ECR5400 (trade name) andECR179EX (trade name) manufactured by Exxon Corporation; and QuintonDX390 (trade name) manufactured by Zeon Corporation. These commerciallyavailable tackifier resins can be used alone, or in combination.

The hot melt adhesive of the present invention can further include: anoil (D). The oil (D) is blended as a plasticizer for the purpose ofdecrease in melt viscosity of the hot melt adhesive, imparting offlexibility to the hot melt adhesive, and improvement in wettability ofthe hot melt adhesive to an adherend. Blending of the oil (D) enablesspiral coating at low temperature.

Examples of the oil (D) include paraffin-based oils, naphthene-basedoils and aromatic-based oils.

It is possible to use, as the oil (D), commercially available products.Examples thereof include Diana Fresia S32 (trade name), Diana ProcessOil PW-90 (trade name) and Process Oil NS-100 (trade name) manufacturedby Idemitsu Kosan Co., Ltd.; PHAZOL35 (trade name) manufactured by SKLUBRICANTS; KN4010 (trade name) manufactured by PetroChina Company;White Oil Broom 350 (trade name) and DN oil KP-68 (trade name)manufactured by Kukdong Oil & Chemical Co., Ltd.; Enerper M1930 (tradename) manufactured by BP Chemicals Ltd.; Kaydol (trade name)manufactured by Crompton Corporation; and Primol 352 (trade name)manufactured by Esso Corp. These oils (D) can be used alone, or incombination.

The hot melt adhesive of the present invention preferably contains: (E)a wax. As used herein, the “wax” refers to an organic substance having aweight average molecular weight of less than 10,000, which is solid atnormal temperature and becomes liquid when heated, and is commonlyconsidered as a “wax”. There is no particularly limitation on the wax aslong as the hot melt adhesive according to the present invention can beobtained, if it has wax-like properties.

The wax (E) preferably contains: (E1) an olefin wax modified withcarboxylic acid or carboxylic anhydride.

In the present invention, the “(E1) olefin wax modified with carboxylicacid or carboxylic anhydride” refers to an olefin wax which ischemically or physically processed with carboxylic acid or carboxylicanhydride, and there is no particular limitation as long as theobjective hot melt adhesive of the present invention is obtainable.Examples of chemical or physical processing include oxidation,polymerization, blending, synthesis and the like.

Examples of the wax (E1) include a wax which is obtainable by graftpolymerization of carboxylic acid or carboxylic anhydride with an olefinwax; and a wax which is obtainable by copolymerization of carboxylicacid or carboxylic anhydride on synthesizing an olefin wax bypolymerization.

Therefore, the wax may be an olefin wax which is modified as a result ofintroduction of carboxylic acid or carboxylic anhydride into the “olefinwax” using various reactions.

There is no particular limitation on the “carboxylic acid” and/or“carboxylic anhydride” to be used to modify the olefin wax as long asthe objective hot melt adhesive of the present invention is obtainable.

Specific examples of the carboxylic acid or carboxylic anhydride includemaleic acid, maleic anhydride, fumaric acid, fumaric anhydride, itaconicacid, acrylic acid, methacrylic acid and the like. These carboxylicacids and/or carboxylic anhydrides may be used alone, or in combination.Maleic acid and maleic anhydride are preferable, and maleic anhydride isparticularly preferable.

The “carboxylic acid” and/or “carboxylic anhydride” to be used to modifythe olefin wax refers to a wax which is obtainable by copolymerizationof two or more kinds of olefins, and there is no particular limitationas long as the objective wax (E1) according to the present invention isobtainable. Therefore, a wax obtained by homopolymerization of one kindof olefin is not included in the olefin wax.

Specific examples of the olefin wax include a polyethylene wax, apolypropylene wax, a polyethylene/polypropylene wax, apolyethylene/polybutylene wax, a polyethylene/polybutene wax and thelike.

Therefore, the wax (E1) in the present invention is particularlypreferably a polyolefin wax modified with maleic anhydride.

The “wax (E)” can include, in addition to the wax (E1), a base wax, andspecific examples thereof include:

synthetic waxes such as a Fischer-Tropsch wax, a polyolefin wax (forexample, polyethylene wax, polypropylene wax, and apolyethylene/polypropylene wax);

petroleum waxes such as a paraffin wax and a microcrystalline wax; and

natural waxes such as a castor wax.

The above base wax may be modified. A substance to modify the base waxmay be various carboxylic acid derivatives as long as a polar group canbe introduced. Examples of the “carboxylic acid derivative” include:

carboxylic acid esters such as ethyl acetate and vinyl acetate;

acid halides such as benzoyl bromide;

amides such as benzamide, N-methylacetamide and N,N-dimethylformamide;

imides such as succinimide;

acyl azide such as acetyl azide;

hydrazides such as propanoyl hydrazide;

hydroxamic acids such as chloroacetylhydroxamic acid;

lactones such as γ-butyrolactone; and

lactams such as δ-caprolactam.

The modified base wax does not contain: the (E1) olefin wax modifiedwith carboxylic acid or carboxylic anhydride.

In the present invention, the wax (E) preferably contains, in additionto the (E1), a Fischer-Tropsch wax (E2) mentioned as the base wax. The“(E2) Fischer-Tropsch wax” refers to a wax which is synthesized byFischer-Tropsch method and is commonly considered as a Fischer-Tropschwax. The Fischer-Tropsch wax is fractionated from a wax whose componentmolecules have comparatively wide carbon number distribution so thatcomponent molecules have narrow carbon number distribution. Examples oftypical Fischer-Tropsch wax include Sasol H1 (trade name) and Sasol C80(trade name), both of which are commercially available from Sasol Wax.

In the present invention, the melting point of the wax (E1) ispreferably from 100 to 130° C., and the melting point of the base wax,preferably the wax (E2) is preferably from 60 to 90° C. The method forthe measurement of the melting point is the same as that for themeasurement of the melting point of the component (A).

An acid value of the wax (E) is preferably from 5 to 200 mgKOH/g, andmore preferably from 20 to 160 mgKOH/g. The acid value can be measuredin accordance with ASTM D1308 or BWM 3.01A.

If necessary, the hot melt adhesive according to the present inventionmay further contain various additives. Examples of the various additivesinclude a stabilizing agent and a fine particle filler.

The “stabilizing agent” is blended so as to prevent decrease inmolecular weight, occurrence of gelation, coloration, odor and the likeof the hot melt adhesive due to heat, thereby improving stability of thehot melt adhesive, and there is no particular limitation as long as theobjective hot melt adhesive of the present invention is obtainable.Examples of the “stabilizing agent” include an antioxidant and anultraviolet absorber.

The “ultraviolet absorber” is used so as to improve light resistance ofthe hot melt adhesive. The “antioxidant” is used so as to preventoxidative degradation of the hot melt adhesive. There is no particularlimitation on the antioxidant and the ultraviolet absorber, as long asthey are commonly used in disposable products and the below-mentionedobjective disposable products are obtainable.

Examples of the antioxidant include a phenol-based antioxidant, asulfur-based antioxidant and a phosphorus-based antioxidant. Examples ofthe ultraviolet absorber include a benzotriazole-based ultravioletabsorber and a benzophenone-based ultraviolet absorber. It is alsopossible to add a lactone-based stabilizer. These additives can be usedalone, or in combination.

It is possible to use, as the stabilizer, commercially availableproducts. Examples thereof include SUMILIZER GM (trade name), SUMILIZERTPD (trade name) and SUMILIZER TPS (trade name) manufactured by SumitomoChemical Co. Ltd.; IRGANOX 1010 (trade name), IRGANOX HP2225FF (tradename), IRGAFOS 168 (trade name) and IRGANOX 1520 (trade name)manufactured by Ciba Specialty Chemicals Inc.; and JF77 (trade name)manufactured by Johoku Chemical Co., Ltd. These stabilizers can be usedalone, or in combination.

The hot melt adhesive for disposable products of the present inventioncan further include a fine particle filler. The fine particle filler maybe commonly used fine particle filler, and there is no particularlimitation as long as the objective hot melt adhesive of the presentinvention can be obtained. Examples of the “fine particle filler”include mica, calcium carbonate, kaolin, talc, titanium oxide,diatomaceous earth, urea-based resin, styrene beads, calcined clay,starch and the like. These particles preferably have a spherical shape,and there is no particular limitation on the size (diameter in case of aspherical shape).

The hot melt adhesive for disposable products of the present inventioncan be produced by blending the components (A) and (B), optionallyblending the components (C)-(E), if necessary blending the variousadditives, and melting the mixture with heating, followed by mixing.Specifically, the hot melt adhesive can be produced by charging theabove components in a melt-mixing vessel equipped with a stirrer,followed by heating and mixing.

With regard to the hot melt adhesive for disposable products accordingto the present invention, a melt viscosity at 150° C. is preferably7,000 mPa·s or less, more preferably from 1,000 to 6,000 mPa·s, andparticularly preferably from 2,000 to 6,000 mPa·s. The “melt viscosity”is a viscosity of a melt of the hot melt adhesive and is measured by aBrookfield RVT-type viscometer (spindle No. 27).

By controlling the melt viscosity within the above range, the hot meltadhesive is more suitable for low-temperature coating. Furthermore, thehot melt adhesive is uniformly applied to a nonwoven fabric and islikely to penetrate, and thus the adhesive is more suitable for use indisposable products.

As mentioned above, the hot melt adhesive according to the presentinvention can also be employed in paper processing, bookbinding,disposable products and the like, and it is suitable for use indisposable products since it is excellent in adhesion to a nonwovenfabric and a polyethylene film.

The disposable products can be constituted by coating at least one kindof a member selected from a group consisting of a woven fabric, anonwoven fabric, a rubber, a resin, papers and a polyolefin film withthe hot melt adhesive according to the present invention. The polyolefinfilm is preferably a polyethylene film for the reason of durability,costs and the like.

There is no particular limitation on the disposable products as long asthey are so-called sanitary materials. Specific examples thereof includea paper diaper, a sanitary napkin, a pet sheet, a hospital gown, asurgical white garment and the like.

In the production line of the disposable products, various members (forexample, tissue, cotton, nonwoven fabric, polyolefin film, etc.) of thedisposable products are commonly coated with the hot melt adhesive. Incase of coating, the hot melt adhesive may be discharged (or ejected)from various dischargers (or ejectors).

There is no particular limitation on the method of coating with the hotmelt adhesive as long as the objective disposable products can beobtained. Such a coating method is roughly classified into a contactcoating method and a non-contact coating method. The “contact coating”method refers to a coating method in which a discharger is brought intocontact with a member or a film in case of coating with the hot meltadhesive, while the “non-contact coating” method refers to a coatingmethod in which a discharger is not brought into contact with a memberor a film in case of coating with the hot melt adhesive. Examples of thecontact coating method include a slot coater coating method, a rollcoater coating method and the like, and examples of the non-contactcoating method include a spiral coating capable of coating in a spiralform, an omega coating or control seam coating method capable of coatingin a wavy form, a slot spray coating or curtain spray coating methodcapable of coating in a plane form, and dot coating capable of coatingin a dot form.

The hot melt adhesive of the present invention is suitable for thespiral coating. The spiral coating method is a method in which anadhesive is applied by intermittent or continuous application, whereinair is supplied to form a spiral adhesive and the adhesive is applied toa member (or a base material) without contact.

It is extremely useful for the production of the disposable productsthat the hot melt adhesive can be applied in a wide width by the spraycoating. The hot melt adhesive capable of being applied in a wide widthis capable of decreasing the coating width by adjusting pressure of thehot air.

When it is difficult to apply the hot melt adhesive in a wide width, alot of spray nozzles for obtaining sufficient bonding area are required,and thus it is unsuitable for the production of comparatively smalldisposable products such as a urine collection liner, and disposableproducts having a complicated shape.

Therefore, the hot melt adhesive of the present invention is suitablefor the disposable products since the spiral coating can be performed ina wide width.

The hot melt adhesive of the present invention is useful for theproduction of the disposable products because of satisfactorycoatability at 150° C. or lower. In case of coating with the hot meltadhesive at a high temperature, since a polyethylene film as a basematerial of the disposable products may be melted and shrink thermally,the appearance of the disposable products is drastically impaired. Incase of applying the hot melt adhesive at 150° C. or lower, theappearance of a nonwoven fabric and the polyethylene film as a basematerial of the disposable products scarcely change and thus theappearance of the products is not impaired.

The hot melt adhesive of the present invention is suitable for theproduction of the disposable products within a short time since it isexcellent in high-speed coatability. When the base material to betransported at a high speed is coated with the hot melt adhesive,breakage of the base material due to friction sometimes arises in thecontact type coating method. The hot melt adhesive of the presentinvention is suitable for the spiral coating as a kind of non-contactcoating and is therefore suited for high-speed coating, and thus it ispossible to improve production efficiency of the disposable products.Furthermore, the hot melt adhesive of the present invention suited forhigh-speed coating minimizes disorder of the coating pattern.

The hot melt adhesive of the present invention has satisfactory thermalstability and is uniformly melted in a high-temperature tank at from 100to 200° C. and does not cause phase separation. A hot melt adhesivehaving poor thermal stability easily cause phase separation ofcomponents in the high-temperature tank. The phase separation can causeclogging of a tank filter and a transfer piping.

Main embodiments of the present invention are shown below.

1. A hot melt adhesive including: (A) a propylene homopolymer having amelting point of 100° C. or lower which is obtainable by polymerizingpropylene using a metallocene catalyst; and (B) an ethylene-basedcopolymer.

2. The hot melt adhesive according to the above 1, wherein theethylene-based copolymer (B) is an ethylene/α-olefin copolymer which isobtainable by polymerization using a metallocene catalyst.

3. The hot melt adhesive according to the above 2, wherein theethylene/α-olefin copolymer (B) contains at least one selected from anethylene/propylene copolymer and an ethylene/octene copolymer.

4. The hot melt adhesive according to any one of the above 1 to 3,further including: (C) a tackifier resin; and (D) an oil.

5. The hot melt adhesive according to any one of the above 1 to 4,further including: (E) a wax, wherein the wax (E) includes a waxmodified with carboxylic acid and/or carboxylic anhydride.

6. The hot melt adhesive according to any one of the above 1 to 5,wherein the adhesive has a melt viscosity at 150° C. of 7,000 mPa·s orless.

7. Disposable products obtainable by using the hot melt adhesiveaccording to any one of the above 1 to 6.

EXAMPLES

The present invention will be descried for the purpose of describing thepresent invention in more detailed and specific manner by way ofExamples. These are exemplary of the present invention and are not to beconsidered as limiting.

Components for blending (or formulating) a hot melt adhesive are shownbelow.

(A) Propylene homopolymer having a melting point 100° C. or lower whichis obtained by polymerization using a metallocene catalyst

(A1) Propylene homopolymer having a melting point of 75° C. and a weightaverage molecular weight of 45,000, manufactured by Idemitsu Kosan Co.,Ltd. under the trade name of “L-MODU X400S”

(A2) Propylene homopolymer having a melting point of 80° C. and a weightaverage molecular weight of 70,000, manufactured by Idemitsu Kosan Co.,Ltd. under the trade name of “L-MODU X600S”

(A′3) Propylene homopolymer having a melting point of 145° C. obtainedby polymerization using a metallocene catalyst, manufactured by ClariantK.K. under the trade name of “Pliocene PP6102”

(A′4) Propylene homopolymer having a melting point of 145° C. obtainedby polymerization using a Ziegler-Natta catalyst, manufactured byEastman Chemical Company under the trade name of “Eastoflex P1010”

(A′5) Polyethylene homopolymer having a melting point of 128° C.obtained by polymerization using a metallocene catalyst, manufactured byClariant K.K. under the trade name of “Licocene PE4201GR”

(B) Ethylene-based copolymer

(B1) Propylene/ethylene copolymer having a melt index of 200 (g/10minutes: 230° C.) obtained by polymerization using a metallocenecatalyst, manufactured by Exxon Mobil Corporation under the trade nameof “Vistamaxx 2330”

(B2) Propylene/ethylene copolymer having a melt index of 20 (g/10minutes: 230° C.) obtained by polymerization using a metallocenecatalyst, manufactured by Exxon Mobil Corporation under the trade nameof “Vistamaxx 6202”

(B3) Propylene/ethylene copolymer (having a random copolymerizationstructure of propylene/ethylene) having a melt index of 25 (g/10minutes: 230° C.) obtained by polymerization using a metallocenecatalyst, manufactured by Dow Chemical Company under the trade name of“VERSIFY 4301”

(B4) Ethylene/octene copolymer (having a block structure ofethylene/octene) having a melt index of 15 (g/10 minutes: 190° C.) whichis obtained by polymerization using a metallocene catalyst, manufacturedby Dow Chemical Company under the trade name of “INFUSE 9807”

(B5) Ethylene/octene copolymer (having a random copolymerizationstructure of ethylene/octene) having a melt index of 13 (g/10 minutes:190° C.) obtained by polymerization using a metallocene catalyst,manufactured by Dow Chemical Company under the trade name of “ENGAGE8137”

(B6) Ethylene/octene copolymer (having a random copolymerizationstructure of ethylene/octene) having a melt index of 500 (g/10 minutes:190° C.) obtained by polymerization using a metallocene catalyst,manufactured by Dow Chemical Company under the trade name of “AFFINITYGA1950”

(B7) Propylene/ethylene copolymer “REXtac 2780A” (trade name),manufactured by Huntsman Corp., which is obtained by polymerizationusing a Ziegler-Natta catalyst

(B8) Propylene/ethylene/butene copolymer obtained by polymerizationusing a Ziegler-Natta catalyst, manufactured by Evonik under the tradename of “VESTOPLAST 703”

(B9) Ethylene/vinyl acetate copolymer obtained by polymerization using aZiegler-Natta catalyst, manufactured by TOSOH CORPORATION under thetrade name of “Ultracene 722”

(B10) Propylene/butene copolymer obtained by polymerization using aZiegler-Natta catalyst, manufactured by Huntsman Corp. under the tradename of “REXtac 2780A”

(B′11) Acrylic copolymer, manufactured by Mitsubishi Rayon Co., Ltd.under the trade name of “BR-106”

(C) Tackifier resin

(C1) Hydrogenated dicyclopentadiene-based resin, manufactured by ExxonMobil Corporation under the trade name of “ECR179EX”

(C2) Hydrogenated dicyclopentadiene-based resin, manufactured by ExxonMobil Corporation under the trade name of “ECR5400”

(C3) Hydrogenated cyclic aliphatic petroleum hydrocarbon resinmanufactured by Arakawa Chemical Industries, Ltd. under the trade nameof “Alcon M100”

(C4) Hydrogenated cyclic aliphatic petroleum hydrocarbon resinmanufactured by Arakawa Chemical Industries, Ltd. under the trade nameof “Alcon P100”

(C5) Unhydrogenated aliphatic aromatic copolymer-based resinmanufactured by Zeon Corporation under the trade name of “QuintoneDX390N”

(C6) Hydrogenated terpene-based resin manufactured by YASUHARA CHEMICALCO., LTD. under the trade name of “Clearon M105”

(D) Oil

(D1) Paraffin oil, manufactured by Idemitsu Kosan Co., Ltd. under thetrade name of “DN Oil KP-68”

(D2) Paraffin oil, manufactured by SK LUBRICANTS under the trade name of“PHAZOL35”

(D3) Paraffin oil, manufactured by Idemitsu Kosan Co., Ltd. under thetrade name of “Diana Process Oil PW-90”

(D4) Paraffin oil, manufactured by Idemitsu Kosan Co., Ltd. “DianaFresia S32”

(D5) Naphthene oil, manufactured by Idemitsu Kosan Co., Ltd. under thetrade name of “Process Oil NS100”

(D6) Naphthene oil, manufactured by PetroChina Company under the tradename “KN4010”

(E) Wax modified with carboxylic acid and/or carboxylic anhydride

(E1) Maleic acid-modified wax, manufactured by Clariant K.K. under thetrade name of “Licocene MA6252TP”

(E2) Fischer-Tropsch wax, manufactured by Sasol under the trade name of“Sasol Wax H-1”

(F) Antioxidant

(F1) Hindered phenol-based antioxidant, manufactured by ADEKACorporation under the trade name of “Adekastab AO-60”

These components (A) to (F) were blended according to the formulationsshown in Tables 1 to 3, and then melt-mixed at about 150° C. over 2hours using a universal stirrer to prepare hot melt adhesives ofExamples 1 to 19 and Comparative Examples 1 to 9. All numerical valueswith respect to the composition (blend) of the hot melt adhesives shownin Tables 1 to 3 are parts by weight.

With respect to the respective hot melt adhesives (Examples andComparative Examples), thermal stability, coatability, high-speedcoatability and peel strength were evaluated. Summary of the respectiveevaluations is described below.

<Thermal Stability>

Thermal stability was evaluated based on the presence or absence ofphase separation of the hot melt adhesive.

Each hot melt adhesive was charged in a glass bottle and left to standat a temperature of 150° C. for 6 hours, and then it was visuallyobserved whether or not phase separation occurs. The weight of each hotmelt adhesive was from 350 to 400 g and a 450 ml volume glass bottle wasused. The glass bottle charged with the hot melt adhesive was left tostand in a dryer after covering with a lid made of aluminum.

After a predetermine time, the hot melt adhesive was taken out, and thepresence or absence of phase separation was visually confirmed quickly.

B: Phase separation was not recognized.

C: Phase separation was recognized.

<Measurement of Melt Viscosity (150° C.)>

The viscosity at 150° C. of each hot melt adhesive was measured inaccordance with the method B defined in JAI7-1991. The measurement wascarried out by a No. 27 rotor using a Brookfield viscometer.

<Coatability>

Using a spiral spray manufactured by Nordson Corporation, a coating basematerial was coated with a hot melt adhesive to produce a laminate ofthe coating base material and an affixing (or laminating) base material,and the coatability was evaluated, and also samples for the evaluationof the below-mentioned peel strength were produced. Both the coatingbase material and the affixing base material are polyethyleneterephthalate (PET) films.

More specifically, the coating base material was coated with the hotmelt adhesive under the conditions of a temperature of each of a hotmelt tank and a spiral spray nozzle of 150° C., a temperature of hot airof 180° C., a pressure of hot air of 0.32 kgf/cm², a discharge amount ofthe hot melt adhesive of 15 g/minute (corresponding to a coating weightof 5 g/m²), a distance between the nozzle and the coating base materialof 35 mm, a transportation speed of the base material of 200 m/minute,an open time of 0.21 second, and a pressure upon pressing after coatingof 2.0 kgf/cm to produce a laminate (PET film/PET film), and then thecoatability was evaluated. The coatability was evaluated by confirming acoating width of the hot melt adhesive applied by spiral coating.Evaluation criteria are shown below.

A: Coating width was 15 mm or more.

B: Coating width was 12 mm or more and less than 15 mm.

C: Coating width was less than 12 mm.

<High-Speed Coatability>

Under the above-mentioned testing conditions of coatability, high-speedcoatability was evaluated.

In the same manner as in the evaluation of coatability, except that thepressure of hot air was changed to 0.45 kgf/cm², a test was carried out.The high-speed coatability was visually evaluated. Evaluation criteriaare as follows.

A: Scatter of the hot melt adhesive was not recognized.

B: Scatter of the hot melt adhesive was slightly recognized.

C: Pattern was not obtained because of scatter of the hot melt adhesive,or coating width of the hot melt adhesive was less than 15 mm.

<Peel Strength>

Using the same test conditions as in the high-speed coatability, samplesof the peel strength were produced.

A conventional nonwoven fabric (SMS of 15 g/m², no surface treatment)was used as the coating base material, and two kinds of (1) aconventional nonwoven fabric (SMS of 15 g/m² no surface treatment) and(2) a conventional polyethylene film (no embossing, 30 g/m², no coronatreatment) were used as an affixing base material.

After aging the samples in the atmosphere at 23° C. under 65% R.H. for24 or more hours, a peel test was carried out under the same atmosphere.The peel test was carried out by Autograph AGS-J manufactured byShimadzu Corporation under the following conditions.

Peel direction: direction which is the same as the direction of movementof the base material (MD) direction, distance between chucks: 20 mm,peel speed: 300 mm/minute Peel length: 50 mm, analysis method: averageof testing force

With each hot melt adhesive (Examples and Comparative Examples), atleast three samples were produced and then measured. The peel strengthwas determined by the obtained average. The peel strength was evaluatedby the following criteria:

(1) Base material to be affixed (or laminated) was a nonwoven fabric(nonwoven fabric/nonwoven fabric)

A: Peel strength was 2.0 N or more.

B: Peel strength was 0.5 N or more and less than 2.0 N.

C: Peel strength was less than 0.5 N.

(2) Base material to be affixed was a polyethylene film (polyethylenefilm/nonwoven fabric)

A: Peel strength was 0.20 N or more.

B: Peel strength was 0.10 N or more and less than 0.20 N.

C: Peel strength was less than 0.10 N.

<Appearance>

When an air-permeable polyethylene film is coated with a hot meltadhesive, a coating pattern of the hot melt adhesive applied inside maybe sometimes seen through from an outside surface of the film. The hotmelt adhesive whose coating pattern is conspicuous is not preferable inview of design properties of disposable products using an air-permeablefilm, and a hot melt adhesive whose coating pattern is inconspicuous isdesired.

In order to evaluate whether or not a coating pattern is conspicuous,the evaluation was carried out by the following procedure.

A 50 μm thick PET film was coated with each hot melt adhesive to form a50 μm thick adhesive layer, and then shaped into a form of 25×10 mm toobtain a test piece. The test piece was affixed (or pasted) to acommercially available air-permeable napkin (ELIS SHIN-SUHADAKAN, NoWing 20.5 cm, manufactured by ELLEAIR PAPER TECH CO., LTD.) and a weightof 1 kg was placed on the affixed part, followed by being left to standin a dryer at 50° C. for 3 days. After a predetermine time, the weightwas removed and change in appearance was confirmed. Evaluation criteriaare as follows:

A: Applied hot melt adhesive was inconspicuous.

B: Applied hot melt adhesive was slightly seen through.

C: Applied hot melt adhesive was seen through.

TABLE 1 Examples 1 2 3 4 5 6 7 8 9 10 11 (A) (A1) 23 33 47 86 33 33 7538 40 75 (A2) 80 66 50 31 50 50 38 40 (A′3) (A′4) (A′5) (B) (B1) 17 (B2)20 11 17 22 14 (B3) 17 (B4) (B5) 25 (B6) (B7) 24 (B8) 20 (B9) 25 (B′11)(B′12) (C) (C1) 140 25 (C2) 66 130 63 130 24 (C3) 60 20 (C4) 60 25 (C5)180 63 (C6) (D) (D1) 50 (D2) 40 (D3) 120 31 50 (D4) 33 40 (D5) 56 90 50(D6) 66 100 100 (E) (E1) 3 3 3 3 3 3 3 (E2) 2 (F) (F1) 1 1 1 1 1 1 1 1 11 1 Thermal stability B B B B B B B B B B B Coatability A A A A B B A AA A A Coating width 17 17 15 15 14 13 15 15 17 17 17 (mm) Melt viscosityat 2,250 2,380 3,380 3,950 5,450 3,380 2,700 5,010 2,500 4,450 1,880150° C. (m · Pas) High-speed B B A A A A B B B B B coatability Scatterof hot B B A A A A B B B B B melt adhesive Coating width 20 18 17 17 1616 20 17 18 18 19 (mm) Peel strength B B A A B A A B B B B (1)Lamination Nonwoven fabric Peel strength 1.20 1.71 2.63 3.40 0.63 3.233.34 1.84 1.99 1.43 1.85 (N) Peel state Cohesive Cohesive MaterialMaterial Cohesive Material Material Cohesive Material Cohesive Materialfracture fracture fracture fracture fracture fracture fracture fracturefracture fracture fracture (1) Lamination A A A A B B B A B B BPolyethylene film Peel strength 0.60 0.45 0.22 0.34 0.11 0.12 0.18 0.380.10 0.14 0.19 (N) Peel state Interfacial Interfacial InterfacialInterfacial Interfacial Interfacial Interfacial Interfacial InterfacialInterfacial Interfacial peel peel peel peel peel peel peel peel peelpeel peel

TABLE 2 Comparative Examples 1 2 3 4 5 7 8 9 (A) (A1) 50 100 (A2) 50 100(A′3) 90 (A′4) 50 (A′5) 50 (B) (B1) (B2) 50 100 (B3) (B4) 50 10 (B5)(B6) (B7) (B8) (B9) (B′11) 50 (B′12) 50 (C) (C1) 80 (C2) 20 (C3) 40 (C4)20 150 (C5) 50 (C6) 100 (D) (D1) 20 150 (D2) 60 40 (D3) 50 (D4) 50 (D5)60 (D6) 80 (E) (E1) (E2) (F) (F1) 2 2 2 2 1 2 2 2 Thermal stability B CB C C B B B Coatability C C C — — A B C Coating width 10 — 10 — — 17 2210 (mm) Melt viscosity at 4,310 6,510 59,800 5,700 230 2,240 1,120116,750 150° C. (m · Pas) High-speed C — C — — B B C coatability Scatterof hot B — B — — B C A melt adhesive Coating width 11 — 11 — — 20 22 11(mm) Peel strength A — A — — B C — (1) Lamination Nonwoven fabric Peelstrength 3.66 — 1.33 — — 0.74 0.40 — (N) Peel state Material — Cohesive— — Cohesive Cohesive — fracture fracture fracture fracture (1)Lamination C — A — — C B — Polyethylene film Peel strength 0.07 — 0.32 —— 0.09 0.21 — (N) Peel state Interfacial — Interfacial — — InterfacialInterfacial — peel peel peel peel

As shown in Table 1, the hot melt adhesives of Examples 1 to 11 areexcellent in thermal stability, coatability and high-speed coatability,and are also excellent in peel strength to a nonwoven fabric, and aretherefore suitable for use in disposable products using a nonwovenfabric, such as a diaper and a napkin.

In contrast, the hot melt adhesives of Comparative Examples 1 to 9 areinferior in any one of the above performances, as shown in Table 2.

TABLE 3 Examples 12 13 14 15 16 17 18 19 (A) (A1) 94 90 80 80 75 70 7560 (A2) (A′3) (A′4) (A′5) (B) (B1) (B2) (B3) (B4) 6 10 20 20 25 30 (B5)25 (B6) 40 (B7) (B8) (B9) (B′11) (B′12) (C) (C1) 60 80 (C2) 40 (C3) 60(C4) 100 85 (C5) 35 (C6) 100 60 (D) (D1) 45 (D2) 40 50 (D3) 40 40 (D4)50 (D5) 40 (D6) 50 (E) (E1) 3 3 (E2) 15 (F) (F1) 2 2 4 2 2 2 2 2 Thermalstability B B B B B B B B Coatability A A A A A B A A Coating width 2020 15 15 15 14 16 17 (mm) Melt viscosity at 3,500 3,630 4,380 5,5603,740 5,990 3,250 3,210 150° C. (m · Pas) High-speed B B A A A A A Bcoatability Scatter of hot B B A A A A A B melt adhesive Coating width20 20 17 16 17 19 19 18 (mm) Peel strength A A A A A A A B (1)Lamination Nonwoven fabric Peel strength 2.88 3.29 3.05 3.98 2.48 4.533.90 0.80 (N) Peel state Material Material Material Material MaterialMaterial Material Material fracture fracture fracture fracture fracturefracture fracture fracture (1) Lamination B B A A A A A B Polyethylenefilm Peel strength 0.10 0.13 0.22 0.40 0.58 0.34 0.40 0.41 (N) Peelstate Interfacial Interfacial Interfacial Interfacial InterfacialInterfacial Interfacial Interfacial peel peel peel peel peel peel peelpeel Appearance A A A A A A A A

As shown in Table 3, the hot melt adhesives of Examples 12 to 19 notonly have the above-mentioned satisfactory performances, but also apattern after coating is inconspicuous. Taking design properties ofdisposable products using an air-permeable film into consideration, thehot melt adhesives of Examples 12 to 19 are extremely excellent fordisposable products.

INDUSTRIAL APPLICABILITY

The present invention provides a hot melt adhesive. The hot meltadhesive according to the present invention is suited for disposableproducts.

The invention claimed is:
 1. A hot melt adhesive, comprising: (A) apropylene homopolymer which has a melting point not higher than 100° C.and is obtainable by polymerizing propylene with a metallocene catalyst;(B) an ethylene-based copolymer; (C) a tackifier resin; and (D) an oil,wherein (A) the propylene homopolymer comprises both (A1) a propylenehomopolymer having weight average molecular weight not more than 60,000and (A2) a propylene homopolymer having weight average molecular weightmore than 60,000, wherein (B) the ethylene-based copolymer comprises anethylene/α-olefin copolymer, and the ethylene/α-olefin copolymercomprises an ethylene/propylene copolymer, and wherein the combined (A)the propylene homopolymer and (B) the ethylene-based copolymer is 100parts by weight of the total weight of the hot melt adhesive; wherein(A) the propylene homopolymer is 60 to 95 parts by weight per 100 partsby weight of the combined (A) the propylene homopolymer and (B) theethylene-based copolymer; wherein (C) the tackifier resin is 20 to 180parts by weight of the total weight of the hot melt adhesive; andwherein (D) the oil is 40 to 120 parts by weight of the total weight ofthe hot melt adhesive.
 2. The hot melt adhesive according to claim 1,wherein (B) the ethylene-based copolymer comprises an ethylene/α-olefincopolymer which is obtainable by polymerization with a metallocenecatalyst, and wherein the ethylene/α-olefin copolymer comprises anethylene/propylene copolymer.
 3. The hot melt adhesive according toclaim 1, wherein the adhesive has a melt viscosity at 150° C. of 7,000mPa·s or less.
 4. The hot melt adhesive according to claim 1, whereinthe adhesive further comprises (E) a wax, and (E) the wax comprises awax modified with a carboxylic acid and/or carboxyl anhydride.
 5. Adisposable product comprising the hot melt adhesive of claim 1.